Corrosion under Insulation (CUI)
CUI is a particularly severe form of localized corrosion that has been plaguing chemical process industries since the energy crisis of the 1970s forced plant designers to include much more insulation in their designs.
Intruding water is the key problem in CUI. Special care must be taken during design not to promote corrosion by permitting water to enter a system either directly or indirectly by capillary action. Moisture may be external or may be present in the insulation material itself. Corrosion may attack the jacketing, the insulation hardware, or the underlying equipment.
For high temperature equipment, water entering an insulation material and diffusing inward will eventually reach a region of dryout at the hot pipe or equipment wall. Next to this dryout region is a zone in which the pores of the insulation are filled with a saturated salt solution. When a shutdown or process change occurs and the metal-wall temperature falls, the zone of saturated salt solution moves into the metal wall.
Upon reheating, the wall will temporarily be in contact with the saturated solution, and stress-corrosion cracking may begin. The drying/wetting cycles in CUI associated problems are a strong accelerator of corrosion damage since they provoke the formation of an increasingly aggressive chemistry that can lead to the worst corrosion problems possible, e.g. stress corrosion cracking, and premature catastrophic equipment failures.