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The detection limits for each technique employed were measured using spiked samples. Instruments were validated by analysing standards at ten different dilutions under reproducible conditions using the same analytical sample on the same day and over different days with different analytical samples; the statistical mean was estimated. The concentrations of the standards were chosen to produce the highest and lowest points on the calibration line. The method detection limits for ICP-MS and AAS were 0.031 mgL1 and 0.061 mgL1, respectively, with their limits of quantification corresponding to 0.11 mgL1 and 0.23 mgL1, respectively.
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