These were formed by agglomerating polycrystalline WO 3 particles of 10–30nm along the axial direction. Furthermore, a measured pore-size distribution indicated that this nanofiber mat had different types of meso-sized porosities, which may have resulted from their wormhole-like structures and inter-fiber voids. In addition, it was observed to have the intra-grain porosity with the diameter of about 1.0nm.